I've been playing around with chocolate chip coookies recently (I like them, and they freeze so well before baking for a warm, impromptu late night treat). The last recipe I tried was the "chewy" cookie recipe from the magisterial King Arthur Flour Cookbook (really - if you don't have this cookbook in your library, purchase it now). I realized in the middle of whipping the butter and sugar, however, that I didn't have corn syrup. I'm not really sure what corn syrup is meant to do anyway (I suppose I should look), but I rooted through my pantry and found this crema di balsamico. Even if it didn't replace the corn syrup's function, I thought, it might heighten the molasses flavor that to me stands at the center of chocolate chip cookie perfect-hood (this after several experiments where I used white sugar instead of the canonical brown sugar - it's not as good).
I think it gave the cookies a certain something, but maybe that's bias.
The King Arthur cookbook recommends baking a test cookie to see how it spread. What a great idea - I was able to add a little flour to save this cookies, after the test cookie spread like an oil slick in the Pacific.

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